Determination of micro amount of water in organic liquids by Karl Fischer method

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Measuring water content of feces by the Karl Fischer method.

We describe a technique for measuring the water content of stools by the Karl Fischer method. The analysis is based on removal of water into a mixture of methanol/chloroform (1/2), after dispersion of the stool by sonication in presence of solvent. An aliquot of the solution thus obtained is placed in themeasuring cell of a Karl Fischer apparatus and then analyzed in the classic way. We further...

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multiwavelength pectrophotometric determination of stability constants of 4-(2– thiazolylazo) resorcinol (tar) with la3+, y3+ and th4+ in organic-water mixed solvents by chemometrics method & simultaneous spectrophotometric determination of lead, copper and nickel using xylenol orange by partial least squares calibration method

تشکیل کمپلکس های tarبا یون های لانتانیم, ایتریم و توریم در دمای 25 درجه، قدرت یونی ثابت 0.1 مولار و در ph ثابت در مخلوط حلال های اتانول – آب و استونیتریل – آب با استفاده از روش های اسپکتروفوتومتری مورد بحث و بررسی قرار گرفت. داده های اسپکتروفوتومتری با استفاده از نرم افزار squad پردازش شدند تا ثابت های تشکیل کمپلکس اندیکاتور – فلز را محاسبه کند. نتایج نشان می دهد که درصد حلال آلی در مخلوط حلال ...

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Simple Modification of Karl-Fischer Titration Method for Determination of Water Content in Colored Samples

The most commonly used technique for water content determination is Karl-Fischer titration with electrometric detection, requiring specialized equipment. When appropriate equipment is not available, the method can be performed through visual detection of a titration endpoint, which does not enable an analysis of colored samples. Here, we developed a method with spectrophotometric detection of a...

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Determination of water in organic solvents by flow-injection analysis with Karl Fischer reagent and a biamperometric detection system.

A flow-injection system with a biamperometric flow-through detector provided with two platinum plate electrodes was tested for the determination of water with a two-component pyridine-free Karl Fischer reagent. The response was shown to be linear in the concentration range 0.03-0.11% water in methanol, ethanol or 2-propanol, with methanol as the carrier solvent. The maximum sampling frequency w...

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Water Determination in Bee Products Using the Karl Fischer Titration Method

One of the most widely used techniques for water content determination in food is Karl Fischer (KF) titration. Compared to other methods based on loss of weight, the primary advantage of the Karl Fischer titration method is its high selectivity to water. The aim of the study was to develop and validate the Karl Fischer method for moisture determination in pollen loads, royal jelly, bee venom an...

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ژورنال

عنوان ژورنال: BUNSEKI KAGAKU

سال: 1971

ISSN: 0525-1931

DOI: 10.2116/bunsekikagaku.20.975